Plutonium(III) phosphate is an inorganic compound of plutonium, with the molecular formula PuPO4. It is the trivalent plutonium salt of phosphoric acid.
Preparation Heating a mixture of plutonium dioxide and diammonium phosphate to 1000°C for 12 hours produces polycrystalline plutonium phosphate.
2 PuO2 + 2 (NH4)2HPO4 → 2 PuPO4 + 4 NH3 + 3 H2O + 1/2 O2 Heating the product to 1100°C produces plutonium dioxide and phosphorus pentoxide. Reacting plutonium(IV) nitrate with disodium phosphate produces PuP2O7 which is decomposed to plutonium phosphate when heated to 600°C for 6 hours in an argon/hydrogen atmosphere.
Pu(NO3)4 + 2 Na2HPO4 → PuP2O7 + 4 NaNO3 + H2O 4 PuP2O7 → 4 PuPO4 + 2 P2O5 + O2 2 PuP2O7 + H2 → 2 PuPO4 + P2O5 + H2O Reacting plutonium(III) fluoride with boron phosphate also produces plutonium phosphate.
PuF3 + BPO4 → PuPO4 + BF3
Properties Plutonium phosphate crystalizes in the monazite crystal structure. It does not dissolve in water.
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