Plutonium(III) phosphide is a binary inorganic compound of plutonium and phosphorus with the formula PuP.
Synthesis Fusion of excess phosphorus and powdered plutonium, followed by distillation of unreacted phosphorus:
4 Pu + P4 → 4 PuP Passing phosphine through heated plutonium hydride:
PuH3 + PH3 → PuP + 3 H2
Physical properties Plutonium(III) phosphide forms black crystals of a cubic system, space group Fm3m, cell parameters a = 0.5660 nm, Z = 4, structure of the NaCl type.
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