Plutonium oxychloride is an inorganic compound of plutonium, oxygen, and chlorine with the chemical formula PuOCl.
Synthesis It is produced in a reaction of plutonium(III) oxide with calcium chloride:
Pu2O3 + CaCl2 → 2PuOCl + CaO It is also formed in trace quantities in the reaction between plutonium trichloride and calcium oxide, which mainly produces plutonium monoxide:
PuCl3 + CaO → PuOCl + CaCl2 The compound is also synthesized by heating PuCl3·6H2O in a sealed tube, or by treating PuO2 or PuCl3 at 650 °C with a vapour mixture prepared via bubbling H2 through aqueous HCl.
Physical properties Plutonium oxychloride appears as a green or blue-green crystals (space group P4/nmm) that are insoluble in water but dissolve in dilute acidic solutions. X-ray diffraction analysis of PuOCl reveals a tetragonal crystal structure, with two molecules present in each unit cell.
Chemical properties PuOCl reacts with calcium (dissolved in liquid calcium chloride) or high-temperature barium vapour to form plutonium monoxide.
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