Plutonyl chloride is an compound of plutonium, oxygen, and chlorine with the chemical formula PuO2Cl2. It is an inorganic compound featuring one plutonium atom in the +6 oxidation state, along with two oxygen atoms and two chlorine atoms. It was initially isolated by Alenchikova et al. in 1959.
Synthesis The plutonyl chloride solution can be prepared by oxidizing tetravalent plutonium chloride with chlorine. The plutonyl chloride is then isolated by evaporation of the solution in vacuum at room temperature.
Physical properties Plutonyl chloride is soluble in water. It is known as the hexahydrate PuO2Cl2·6H2O, an unstable solid which decomposes to a plutonium(IV) compound over time via alpha radiation from the plutonium.
Uses Plutonyl chloride and its complexes are important in the context of nuclear fuel reprocessing.
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