Polonium tetraiodide is a binary inorganic compound of polonium and iodine with the chemical formula PoI4. The compound forms volatile black crystals.
Synthesis 1. Action of iodine vapor on polonium metal:
Po + 2 I2 → PoI4 2. Dissolution of polonium dioxide in hydroiodic acid:
PoO2 + 4 HI → PoI4 + 2 H2O
Properties
Physical properties The compound forms black crystals that are insoluble in water.
Chemical properties The compound reacts with hydroiodic acid to form hexaiodopolonic acid:
PoI4 + 2 HI → H2[PoI6] It can be reduced by hydrogen sulfide to yield polonium metal. It decomposes on heating.
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