Potassium antimonide is a binary inorganic compound of potassium and antimony with the molecular formula K3Sb.
Synthesis The compound is synthesized by fusing the elements:
3K + Sb → K3Sb
Physical properties The compound forms yellow-green crystals of the hexagonal crystal system, space group P63/mmc. A cubic form of K3Sb can be obtained as a thin film by first oxidizing the surface of an antimony layer before introducing potassium.
Chemical properties Potassium antimonide reacts with water, producing stibine and potassium hydroxide:
K3Sb + 3H2O → H3Sb + 3KOH
Uses The compound is recognized for its applications in electronics, particularly within photocathodes and photomultiplier tubes. Its capacity to release electrons upon light exposure renders it essential in equipment that depends on effective photoemission.
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