Potassium hexabromorhenate is an inorganic chemical compound with the chemical formula K2ReBr6.
Synthesis Fusion of rhenium with potassium bromide in a bromine vapor current:
Re + 2KBr + 2Br2 → K2ReBr6 The effect of hydrobromic acid on a mixture of potassium bromide with rhenium(IV) oxide:
ReO2 + 2KBr + 4HBr → K2ReBr6 + 2H2O Reduction of potassium perrenate by potassium iodide in concentrated hydrobromic acid:
2KReO4 + 6KI + 16HBr → 2K2ReBr6 + 4KBr + 3I2 + 8H2O
Chemical properties Potassium hexabromorhenate dissolves in hydrobromic acid to create a red or deep yellow solution. Reacts with water.
K2ReBr6 + 2H2O → ReO2 + 2KBr + 4HBr
Physical properties The compound forms dark red crystals of cubic system, space group Fm3m.
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