Potassium hexaiodorhenate is an inorganic chemical compound with the chemical formula K2ReI6.
Synthesis The compound can be prepared by reduction of potassium perrhenate by potassium iodide in concentrated hydrochloric acid:
2KReO4 + 2KI + 16HI → 2KReI6 + 3I2 + 8H2O
Physical properties The compound forms black crystals, soluble in warm HI, methanol, and acetone.
Chemical properties Potassium hexaiodorhenate is hydrolyzed in aqueous solutions.
K2ReI6 + 2H2O → ReO2 + 2KI + 4HI It decomposes when heated:
K2ReI6 → Re + 2KI + 2I2 It reacts with strong acids:
K2ReI6 + H2SO4 → HReI5 + HI + K2SO4
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