Potassium tetrachloropalladate(II) is an inorganic compound with the chemical formula K2PdCl4. It is a dark brown solid, forming tetragonal crystals.
Synthesis Potassium tetrachloropalladate(II) can be prepared by passing chlorine through a palladium black suspension in a concentrated potassium chloride solution:
Pd + Cl2 + 2KCl → K2[PdCl4] It can also be prepared by mixing concentrated solutions of palladium(II) chloride and potassium chloride:
PdCl2 + 2KCl → K2[PdCl4] It forms in the decomposition of potassium hexachloropalladate(IV):
K2[PdCl6] → K2[PdCl4] + Cl2
Uses The compound is used in the gelation of colloidal semiconductor nanocrystals.
Reactions The compound reacts with aqua regia forming potassium hexachloropalladate(IV):
3K2[PdCl4] + 6HCl + 2HNO3 → 3K2[PdCl6] + 2NO + 4H2O
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