Potassium tetrafluoroborate is an inorganic compound with the formula KBF4. It is a colorless, odorless crystalline powder, and crystallizes into orthorhombic space group Pnma.
Preparation Potassium fluoroborate is obtained by adding a solution of potassium hydroxide (KOH) to a cold solution of boric acid (H3BO3) in 40% hydrofluoric acid (HF) in a platinum dish:
H3BO3 + 4 HF + KOH → KBF4 + 4 H2O
Reactions Potassium tetrafluoroborate has been reacted with molten lithium chloride (LiCl), sodium chloride (NaCl), and potassium chloride (KCl). Lithium ions cause the decomposition of tetrafluoroborate leading to the production of BCl3 gas. The other liquid alkali chlorides do not decompose the tetrafluoroborate, even though they are at higher temperatures. It may be used to produce boron trifluoride (BF3) by heating the molten salt with boron trioxide (B2O3) at 600 °C (1,112 °F) in an iron tube connected to a drying tube filled with dry potassium fluoride (KF) followed by a liquid nitrogen cooled trap:
KBF4 + 2 B2O3 → BF3 + KF·B4O6 The collected impure BF3 is purified via fractional distillation.
Uses Potassium tetrafluoroborate is used in p-type semiconductor doping to introduce boron into the silicon lattice in an easily controlled way. It is also used in etching solutions for silicon wafers and as a soldering flux in high temperature soldering.
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