Potassium tetraiodoplatinate is the inorganic compound with the formula K2PtI4·(H2O)2. It is the potassium salt of tetraiodoplatinate, a square planar complex of platinum(II). The compound crystallizes from water as the dihydrate, whereas the related chloride and bromide K2PtCl4 and K2PtBr4 are obtained only as the anhydrous salts. It reacts with amines and with ammonia to give charge-neutral derivatives PtI2(RNH2)2. The compound is prepared by the salt metathesis reaction of potassium iodide and potassium tetrachloroplatinate:
K2PtCl4 + 4 KI → K2PtI4 + 4 KCl Potassium tetraiodoplatinate is a precursor to the anticancer drug cisplatin.
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