Praseodymium(IV) fluoride (also praseodymium tetrafluoride) is a binary inorganic compound, a highly oxidised metal salt of praseodymium and fluoride with the chemical formula PrF4.
Synthesis Praseodymium(IV) fluoride can be prepared by the effect of krypton difluoride on praseodymium(IV) oxide:
P r O 2 + 2 K r F 2 → P r F 4 + O 2 + 2 K r {\displaystyle {\mathsf {PrO_{2}+2KrF_{2}\ {\xrightarrow {}}\ PrF_{4}+O_{2}+2Kr}}}
Praseodymium(IV) fluoride can also be made by the dissolution of sodium hexafluoropraseodymate(IV) in liquid hydrogen fluoride:
N a 2 [ P r F 6 ] + 2 H F → P r F 4 ↓ + 2 N a H F 2 {\displaystyle {\mathsf {Na_{2}[PrF_{6}]+2HF\ {\xrightarrow {}}\ PrF_{4}\downarrow +2NaHF_{2}}}}
Properties Praseodymium(IV) fluoride forms light yellow crystals. The crystal structure is anticubic and isomorphic to that of uranium tetrafluoride UF4. It decomposes when heated:
2 P r F 4 → 90 o C 2 P r F 3 + F 2 {\displaystyle {\mathsf {2PrF_{4}\ {\xrightarrow {90^{o}C}}\ 2PrF_{3}+F_{2}}}}
Due to the high normal potential of the tetravalent praseodymium cations (Pr3+ / Pr4+: +3.2 V), praseodymium(IV) fluoride decomposes in water, releasing oxygen, O2.
See also Praseodymium(III) fluoride Uranium tetrafluoride
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