Promethium(III) sulfide is a binary inorganic compound with the chemical formula Pm2S3.
Synthesis Promethium(III) sulfide can be produced by treating metallic promethium with sulfur:
2Pm + 3S → Pm2S3 Once prepared, promethium(III) sulfide can be purified by chemical vapor transport using iodine. Promethium(III) sulfide can also be prepared by treating the sulfate with hydrogen sulfide at elevated temperatures:
Pm2(SO4)3 + 12 H2S → Pm2S3 + 12 H2O + 12 S
Physical properties The compound forms garnet red crystals of the orthorhombic system, space group I43d and exists in α and β forms.
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