Protactinium tetrafluoride is a binary inorganic compound of protactinium metal and fluorine with the chemical formula PaF4.
Synthesis Protactinium tetrafluoride can be obtained by fluorinating protactinium(IV) oxide with a hydrogen fluoride / hydrogen mixture at 600 °C:
PaO2 + 4HF → PaF4 + 2H2O The effect of hydrogen fluoride and hydrogen on protactinium(V) oxide:
Pa2O5 + 8HF + H2 → 2PaF4 + 5H2O
Physical properties PaF4 forms dark brown, monoclinic, needlelike crystals of UF4 structure. The cell parameters are: a = 1.27 nm, b = 1.07 nm, c = 0.842 nm, β = 126.3°. The compound is soluble in aqueous ammonium fluoride solutions.
Chemical properties Protactinium tetrafluoride reacts with oxygen and fluorine:
2PaF4 + F2 → 2PaF5 4PaF4 + O2 → 2Pa2OF8 The compound reacts with alkalis:
PaF4 + 4NaOH → PaO2 + 4NaF + 2H2O The metal is displaced from the salt by barium:
PaF4 + 2Ba → Pa + 2BaF2
References


