Protactinium tetraiodide is a binary inorganic compound of protactinium metal and iodine with the chemical formula PaI4.
Synthesis Protactinium tetraiodide can be prepared by reducing the pentaiodide with aluminum at about 400 °C:
3PaI5 + Al → 3PaI4 + AlI3 Also, a reaction of hydrogen reduction of protactinium(V) iodide at 400 °C:
2PaI5 + H2 → 2PaI4 + 2HI
Physical properties The compound forms black or dark green crystals. The structure is not known.
Chemical properties The compound is oxidized by antimony trioxide when heated in a vacuum:
3PaI4 + Sb2O3 → 3PaOI2 + 2SbI3 The compound also reacts with quartz when heated:
2PaI4 + SiO2 → 2PaOI2 + SiI4
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