In physics, Q {\displaystyle \mathbf {Q} } -tensor is an orientational order parameter that describes uniaxial and biaxial nematic liquid crystals and vanishes in the isotropic liquid phase. The Q {\displaystyle \mathbf {Q} } tensor is a second-order, traceless, symmetric tensor and is defined by
Q = S ( n ⊗ n − 1 3 I ) + R ( m ⊗ m − 1 3 I ) {\displaystyle \mathbf {Q} =S\left(\mathbf {n} \otimes \mathbf {n} -{\tfrac {1}{3}}\mathbf {I} \right)+R\left(\mathbf {m} \otimes \mathbf {m} -{\tfrac {1}{3}}\mathbf {I} \right)}
where S = S ( T ) {\displaystyle S=S(T)} and R = R ( T ) {\displaystyle R=R(T)} are scalar order parameters, ( n , m ) {\displaystyle (\mathbf {n} ,\mathbf {m} )} are the two directors of the nematic phase and T {\displaystyle T} is the temperature; in uniaxial liquid crystals, R = 0 {\displaystyle R=0} . The components of the tensor are
Q i j = S ( n i n j − 1 3 δ i j ) + R ( m i m j − 1 3 δ i j ) {\displaystyle Q_{ij}=S\left(n_{i}n_{j}-{\tfrac {1}{3}}\delta _{ij}\right)+R\left(m_{i}m_{j}-{\tfrac {1}{3}}\delta _{ij}\right)}
The states with directors n {\displaystyle \mathbf {n} } and − n {\displaystyle -\mathbf {n} } are physically equivalent and similarly the states with directors m {\displaystyle \mathbf {m} } and − m {\displaystyle -\mathbf {m} } are physically equivalent. The Q {\displaystyle \mathbf {Q} } -tensor can always be diagonalized,
Q = 1 3 [ 2 S − R 0 0 0 2 R − S 0 0 0 − S − R ] {\displaystyle \mathbf {Q} ={\frac {1}{3}}{\begin{bmatrix}2S-R&0&0\\0&2R-S&0\\0&0&-S-R\\\end{bmatrix}}}
The following are the two invariants of the Q {\displaystyle \mathbf {Q} } tensor,
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