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earth science

Realgar

Realgar is a earth science topic covered in the lgStudy science library. This page brings together a partial reference excerpt, illustrations, worked examples, real-world applications and a short study plan, so you can understand Realgar rather than just read about it. In short: Realgar ( ree-AL-gar, -⁠gər), also known as arsenic blende, ruby sulphur or ruby of arsenic, is an arsenic sulfide mineral with the chemical formula α-As4S4. It is a soft mineral occurring in monoclinic crystals, or in granular, compact, or powdery form, often in association with the related mineral, orpiment (As2S3).

Realgar — main illustration
Realgar — illustration

Key takeaways

  • Realgar belongs to earth science; place it in that map before memorising details.
  • Learn the definition first, then one example that makes the definition concrete.
  • Connect Realgar to a quantity you can measure, compute or draw — that is where exam questions come from.
  • Reproduce the core statement of Realgar from memory before moving on to harder problems.

Reference excerpt

Realgar ( ree-AL-gar, -⁠gər), also known as arsenic blende, ruby sulphur or ruby of arsenic, is an arsenic sulfide mineral with the chemical formula α-As4S4. It is a soft mineral occurring in monoclinic crystals, or in granular, compact, or powdery form, often in association with the related mineral, orpiment (As2S3). It is orange-red in color, and burns with a bluish flame releasing fumes of arsenic and sulfur. It is trimorphous with pararealgar and bonazziite.

Etymology Its name comes from the Arabic rahj al-ġār (رهج الغار [rahdʒælɣaːr] , "powder of the mine"), via Medieval Latin, and its earliest record in English is in the 1390s.

Uses Realgar is a minor ore of arsenic extracted in China, Peru, and the Philippines.

Historical uses Realgar was used by firework manufacturers in white flame and star compositions and to produce yellow smoke in daytime fireworks. Realgar has been used to kill weeds, insects, and rodents, even though more effective arsenic-based anti-pest agents are available such as cacodylic acid, (CH3)2As(O)OH, an organoarsenic compound used as an herbicide. Realgar was also used by Ancient Greek apothecaries to make a medicine known as "bull's blood". The Greek physician Nicander described a death by "bull's blood", which matches the known effects of arsenic poisoning. Bull's blood is the poison that is said to have been used by Themistocles and Midas for suicide. The Chinese name for realgar is 雄黃 (Mandarin xiónghuáng), literally 'masculine yellow', as opposed to orpiment which is 'feminine yellow'. Realgar was, along with orpiment, traded in the Roman Empire and was used as a red paint pigment. Early occurrences of realgar as a red paint pigment are known for works of art from China, India, Central Asia, and Egypt. It was used in Venetian fine-art painting during the Renaissance era, though rarely elsewhere in Europe, a use which died out by the 18th century. It was also used as medicine. Other traditional uses include manufacturing lead shot, printing, and dyeing calico cloth. It was used to poison rats in medieval Spain and in 16th century England.

Occurrence Realgar most commonly occurs as a low-temperature hydrothermal vein mineral associated with other arsenic and antimony minerals. It also occurs as volcanic sublimations and in hot spring deposits. It occurs in association with orpiment, arsenolite, calcite and barite. It is found with lead, silver and gold ores in Hungary, Bohemia and Saxony. In the US it occurs notably in Mercur, Utah; Manhattan, Nevada; and in the geyser deposits of Yellowstone National Park. After a long period of exposure to light, realgar changes form to a yellow powder known as pararealgar (β-As4S4). It was once thought that this powder was the yellow sulfide (orpiment), but is a distinct chemical compound.

Gallery

See also

Classification of minerals List of inorganic pigments List of minerals Realgar wine or Xionghuang wine is a Chinese alcoholic drink that is made from Chinese liquor dosed with powdered realgar.

References

Further reading Craigie, W.A.; Bradley, H. (1914). "Realgar". In Sir James, A.H. Murray (ed.). A New English Dictionary on Historical Principles. Clarendon Press at Oxford. p. 202 – via archive.org. William Mesny (1899). Mesny's Chinese Miscellany. A Text Book of Notes on China and the Chinese. Vol. III. Shanghai. p. 251. William Mesny (1905). Mesny's Chinese Miscellany. A Text Book of Notes on China and the Chinese. Vol. IV. Shanghai. pp. 425–426.

External links

Mindat.org: Pararealgar

Illustrations

Realgar illustration
Realgar illustration
Realgar illustration
Realgar illustration
Realgar illustration

Worked examples

Example 1 — a first encounter with Realgar

Start with the simplest possible case. Write down what Realgar claims or describes in one sentence, then invent the smallest concrete situation in which that sentence is true. In earth science, the smallest case is usually a single object, a single equation or a single measurement. Check that every symbol or term in your sentence has a meaning in that case.

Example 2 — changing one variable

Take the situation from Example 1 and change exactly one quantity: double it, halve it, or set it to zero. Predict what should happen to Realgar before you calculate. Comparing your prediction with the result is the fastest way to find out whether you understand the idea or only the words.

Example 3 — an exam-style question

Typical questions about Realgar ask you to (a) state it precisely, (b) apply it to given data, and (c) explain a limitation. Practise writing all three answers in under five minutes; the third part is what separates a full-mark answer from an average one.

Applications of Realgar

In research
Realgar appears in earth science research whenever the underlying quantities have to be modelled precisely. Papers usually cite it as a starting assumption and then explore where it breaks down.
In technology and industry
Engineering practice reuses Realgar in design rules, simulations and safety margins. Knowing the idea lets you read a specification sheet and understand why the numbers look the way they do.
In the classroom
Realgar is common in secondary-school and first-year university syllabi. It links to neighbouring topics Alchemical substances, Arsenic minerals, Blendes, so understanding it makes those chapters shorter.
In everyday life
Look for Realgar outside the textbook — in sport, cooking, traffic, electronics or the sky above you. An example you found yourself is remembered far longer than one you were given.

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How to study Realgar in 20 minutes

  1. Read the reference excerpt below once, without taking notes.
  2. Close the page and write down what Realgar means in your own words.
  3. Compare your version with the excerpt and mark what you missed.
  4. Work through the three examples above with pen and paper.
  5. Explain Realgar out loud to somebody else — or to Teacher Smith in the lgStudy chat.

Frequently asked questions

What is Realgar in simple terms?

Realgar ( ree-AL-gar, -⁠gər), also known as arsenic blende, ruby sulphur or ruby of arsenic, is an arsenic sulfide mineral with the chemical formula α-As4S4. It is a soft mineral occurring in monoclinic crystals, or in granular, compact, or powdery form, often in association with the related minera…

Why does Realgar matter?

Because it connects several earth science ideas at once: it gives you a definition you can apply, a quantity you can calculate, and a way to check whether a result is plausible.

How should I study Realgar?

Read the excerpt, restate it from memory, then work through the examples and applications listed on this page. The five-step study plan above takes about twenty minutes.

What does this page cover?

It gives you a compact reference excerpt plus original lgStudy explanations, examples, applications and study material on Realgar.

Tags

  • Alchemical substances
  • Arsenic minerals
  • Blendes
  • Inorganic pigments
  • Minerals in space group 14
  • Monoclinic minerals
  • Sulfide minerals

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