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Representative elementary volume

Representative elementary volume is a chemistry topic covered in the lgStudy science library. This page brings together a partial reference excerpt, illustrations, worked examples, real-world applications and a short study plan, so you can understand Representative elementary volume rather than just read about it. In short: In the theory of composite materials, the representative elementary volume (REV) (also called the representative volume element (RVE) or the unit cell) is the smallest volume over which a measurement can be made that will yield a value representative of the whole. In the case of periodic materials, one simply chooses a periodic unit cell (which, however, may be non-unique), but in random media, the situation is much…

Representative elementary volume — main illustration
Representative elementary volume — illustration

Key takeaways

  • Representative elementary volume belongs to chemistry; place it in that map before memorising details.
  • Learn the definition first, then one example that makes the definition concrete.
  • Connect Representative elementary volume to a quantity you can measure, compute or draw — that is where exam questions come from.
  • Reproduce the core statement of Representative elementary volume from memory before moving on to harder problems.

Reference excerpt

In the theory of composite materials, the representative elementary volume (REV) (also called the representative volume element (RVE) or the unit cell) is the smallest volume over which a measurement can be made that will yield a value representative of the whole. In the case of periodic materials, one simply chooses a periodic unit cell (which, however, may be non-unique), but in random media, the situation is much more complicated. For volumes smaller than the RVE, a representative property cannot be defined and the continuum description of the material involves Statistical Volume Element (SVE) and random fields. The property of interest can include mechanical properties such as elastic moduli, hydrogeological properties, electromagnetic properties, thermal properties, and other averaged quantities that are used to describe physical systems.

Definition

Rodney Hill defined the RVE as a sample of a heterogeneous material that:

"is entirely typical of the whole mixture on average", and "contains a sufficient number of inclusions for the apparent properties to be independent of the surface values of traction and displacement, so long as these values are macroscopically uniform." In essence, statement (1) is about the material's statistics (i.e. spatially homogeneous and ergodic), while statement (2) is a pronouncement on the independence of effective constitutive response with respect to the applied boundary conditions. Both of these are issues of mesoscale (L) of the domain of random microstructure over which smoothing (or homogenization) is being done relative to the microscale (d). As L/d goes to infinity, the RVE is obtained, while any finite mesoscale involves statistical scatter and, therefore, describes an SVE. With these considerations one obtains bounds on effective (macroscopic) response of elastic (non)linear and inelastic random microstructures. In general, the stronger the mismatch in material properties, or the stronger the departure from elastic behavior, the larger is the RVE. The finite-size scaling of elastic material properties from SVE to RVE can be grasped in compact forms with the help of scaling functions universally based on stretched exponentials. Considering that the SVE may be placed anywhere in the material domain, one arrives at a technique for characterization of continuum random fields. Another definition of the RVE was proposed by Drugan and Willis:

"It is the smallest material volume element of the composite for which the usual spatially constant (overall modulus) macroscopic constitutive representation is a sufficiently accurate model to represent mean constitutive response." The choice of RVE can be quite a complicated process. The existence of a RVE assumes that it is possible to replace a heterogeneous material with an equivalent homogeneous material. This assumption implies that the volume should be large enough to represent the microstructure without introducing non-existing macroscopic properties (such as anisotropy in a macroscopically isotropic material). On the other hand, the sample should be small enough to be analyzed analytically or numerically.

Examples

For mechanical properties

In continuum mechanics generally for a heterogeneous material, RVE can be considered as a volume V that represents a composite statistically, i.e., volume that effectively includes a sampling of all microstructural heterogeneities (grains, inclusions, voids, fibers, etc.) that occur in the composite. It must however remain small enough to be considered as a volume element of continuum mechanics. Several types of boundary conditions can be prescribed on V to impose a given mean strain or mean stress to the material element. One of the tools available to calculate the elastic properties of an RVE is the use of the open-source EasyPBC ABAQUS plugin tool. Analytical or numerical micromechanical analysis of fiber reinforced composites involves the study of a representative volume element (RVE). Although fibers are distributed randomly in real composites, many micromechanical models assume periodic arrangement of fibers from which RVE can be isolated in a straightforward manner. The RVE has the same elastic constants and fiber volume fraction as the composite. In general RVE can be considered same as a differential element with a large number of crystals.

For porous media Establishing a given porous medium's properties requires measuring samples of the porous medium. If the sample is too small, the readings tend to oscillate. With increasing sample size, the oscillations begin to dampen out. Eventually the sample size will become large enough that readings are consistent. This sample size is referred to as the representative elementary volume. If sample size is increased further, measurement will remain stable until the sample size gets large enough that it begins to include other hydrostratigraphic layers. This is referred to as the maximum elementary volume (MEV). Groundwater flow equation has to be defined in an REV.

For electromagnetic media

While RVEs for electromagnetic media can have the same form as those for elastic or porous media, the fact that mechanical strength and stability are not concerns allow for a wide range of RVEs. In the adjacent figure, the RVE consists of a split-ring resonator and its surrounding backing material.

Alternatives There does not exist one RVE size and depending on the studied mechanical properties, the RVE size can vary significantly. The concept of statistical volume element (SVE) and uncorrelated volume element (UVE) have been introduced as alternatives for RVE.

Statistical volume element (SVE) Statistical volume element (SVE), which is also referred to as stochastic volume element in finite element analysis, takes into account the variability in the microstructure. Unlike RVE in which average value is assumed for all realizations, SVE can have a different value from one realization to another. SVE models have been developed to study polycrystalline microstructures. Grain features, including orientation, misorientation, grain size, grain shape, grain aspect ratio are considered in SVE model. SVE model was applied in the material characterization and damage prediction in microscale. Compared with RVE, SVE can provide a comprehensive representation of the microstructure of materials.

… excerpt ends here. Continue reading the full article.

Illustrations

Representative elementary volume: Schematic illustration of idealized fiber arrays and their corresponding unit cells.
Schematic illustration of idealized fiber arrays and their corresponding unit cells.
Representative elementary volume illustration
Representative elementary volume illustration
Representative elementary volume illustration
Representative elementary volume illustration

Worked examples

Example 1 — a first encounter with Representative elementary volume

Start with the simplest possible case. Write down what Representative elementary volume claims or describes in one sentence, then invent the smallest concrete situation in which that sentence is true. In chemistry, the smallest case is usually a single object, a single equation or a single measurement. Check that every symbol or term in your sentence has a meaning in that case.

Example 2 — changing one variable

Take the situation from Example 1 and change exactly one quantity: double it, halve it, or set it to zero. Predict what should happen to Representative elementary volume before you calculate. Comparing your prediction with the result is the fastest way to find out whether you understand the idea or only the words.

Example 3 — an exam-style question

Typical questions about Representative elementary volume ask you to (a) state it precisely, (b) apply it to given data, and (c) explain a limitation. Practise writing all three answers in under five minutes; the third part is what separates a full-mark answer from an average one.

Applications of Representative elementary volume

In research
Representative elementary volume appears in chemistry research whenever the underlying quantities have to be modelled precisely. Papers usually cite it as a starting assumption and then explore where it breaks down.
In technology and industry
Engineering practice reuses Representative elementary volume in design rules, simulations and safety margins. Knowing the idea lets you read a specification sheet and understand why the numbers look the way they do.
In the classroom
Representative elementary volume is common in secondary-school and first-year university syllabi. It links to neighbouring topics Continuum mechanics, Hydrogeology, Volume, so understanding it makes those chapters shorter.
In everyday life
Look for Representative elementary volume outside the textbook — in sport, cooking, traffic, electronics or the sky above you. An example you found yourself is remembered far longer than one you were given.

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How to study Representative elementary volume in 20 minutes

  1. Read the reference excerpt below once, without taking notes.
  2. Close the page and write down what Representative elementary volume means in your own words.
  3. Compare your version with the excerpt and mark what you missed.
  4. Work through the three examples above with pen and paper.
  5. Explain Representative elementary volume out loud to somebody else — or to Teacher Smith in the lgStudy chat.

Frequently asked questions

What is Representative elementary volume in simple terms?

In the theory of composite materials, the representative elementary volume (REV) (also called the representative volume element (RVE) or the unit cell) is the smallest volume over which a measurement can be made that will yield a value representative of the whole. In the case of periodic materials…

Why does Representative elementary volume matter?

Because it connects several chemistry ideas at once: it gives you a definition you can apply, a quantity you can calculate, and a way to check whether a result is plausible.

How should I study Representative elementary volume?

Read the excerpt, restate it from memory, then work through the examples and applications listed on this page. The five-step study plan above takes about twenty minutes.

What does this page cover?

It gives you a compact reference excerpt plus original lgStudy explanations, examples, applications and study material on Representative elementary volume.

Tags

  • Continuum mechanics
  • Hydrogeology
  • Volume

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