Rhenium tetraiodide is a binary chemical compound of rhenium and iodide with the chemical formula ReI4.
Synthesis Rhenium tetraiodide can be obtained via the reduction of perrhenic acid with hydrogen iodide:
2HReO4 + 14HI4 → 2ReI4 + 3I2 + 8H2O
Physical properties Rhenium tetraiodide forms black solid substance which is soluble in acetone and ether. Hydrolyzed by water, hygroscopic.
Chemical properties Rhenium tetraiodide is hydrolyzed by water:
ReI4 + 2H2O → ReO2 + 4HI Rhenium tetraiodide decomposes when heated:
ReI4 → ReI3, ReI2, ReI, I2
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