Rhenium trioxide chloride is an inorganic compound with the formula ReO3Cl. It is a colorless, distillable, diamagnetic liquid. It is a rhenium oxychloride. The material is used as a reagent in the preparation of rhenium compounds.
Synthesis and reactions Rhenium trioxide chloride can be prepared by chlorination of rhenium trioxide:
2 ReO3 + Cl2 → 2 ReO3Cl With Lewis bases (L), rhenium trioxide chloride reacts to form adducts with the formula ReO3ClL2. The compound hydrolyzes readily to give perrhenic acid.
Structure The compound adopts a tetrahedral structure with Re-O and Re-Cl bond distances of 1.71 and 2.22 Å. In contrast rhenium trioxide fluoride (ReO3F) is polymeric with octahedral Re centers.
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