Rock magnetism is the study of the magnetic properties of rocks, sediments and soils. The field arose out of the need in paleomagnetism to understand how rocks record the Earth's magnetic field. This remanence is carried by minerals, particularly certain strongly magnetic minerals like magnetite (the main source of magnetism in lodestone). An understanding of remanence helps paleomagnetists to develop methods for measuring the ancient magnetic field and correct for effects like sediment compaction and metamorphism. Rock magnetic methods are used to get a more detailed picture of the source of the distinctive striped pattern in marine magnetic anomalies that provides important information on plate tectonics. They are also used to interpret terrestrial magnetic anomalies in magnetic surveys as well as the strong crustal magnetism on Mars. Strongly magnetic minerals have properties that depend on the size, shape, defect structure and concentration of the minerals in a rock. Rock magnetism provides non-destructive methods for analyzing these minerals such as magnetic hysteresis measurements, temperature-dependent remanence measurements, Mössbauer spectroscopy, ferromagnetic resonance and so on. With such methods, rock magnetists can measure the effects of past climate change and human impacts on the mineralogy (see environmental magnetism). In sediments, a lot of the magnetic remanence is carried by minerals that were created by magnetotactic bacteria, so rock magnetists have made significant contributions to biomagnetism.
History Until the 20th century, the study of the Earth's field (geomagnetism and paleomagnetism) and of magnetic materials (especially ferromagnetism) developed separately. Rock magnetism had its start when scientists brought these two fields together in the laboratory. Koenigsberger (1938), Thellier (1938) and Nagata (1943) investigated the origin of remanence in igneous rocks. By heating rocks and archeological materials to high temperatures in a magnetic field, they gave the materials a thermoremanent magnetization (TRM), and they investigated the properties of this magnetization. Thellier developed a series of conditions (the Thellier laws) that, if fulfilled, would allow the determination of the intensity of the ancient magnetic field to be determined using the Thellier–Thellier method. In 1949, Louis Néel developed a theory that explained these observations, showed that the Thellier laws were satisfied by certain kinds of single-domain magnets, and introduced the concept of blocking of TRM. When paleomagnetic work in the 1950s lent support to the theory of continental drift, skeptics were quick to question whether rocks could carry a stable remanence for geological ages. Rock magnetists were able to show that rocks could have more than one component of remanence, some soft (easily removed) and some very stable. To get at the stable part, they took to "cleaning" samples by heating them or exposing them to an alternating field. However, later events, particularly the recognition that many North American rocks had been pervasively remagnetized in the Paleozoic, showed that a single cleaning step was inadequate, and paleomagnetists began to routinely use stepwise demagnetization to strip away the remanence in small bits.
Fundamentals
Types of magnetic order The contribution of a mineral to the total magnetism of a rock depends strongly on the type of magnetic order or disorder. Magnetically disordered minerals (diamagnets and paramagnets) contribute a weak magnetism and have no remanence. The more important minerals for rock magnetism are the minerals that can be magnetically ordered, at least at some temperatures. These are the ferromagnets, ferrimagnets and certain kinds of antiferromagnets. These minerals have a much stronger response to the field and can have a remanence.
Diamagnetism Diamagnetism is a magnetic response shared by all substances. In response to an applied magnetic field, electrons precess (see Larmor precession), and by Lenz's law they act to shield the interior of a body from the magnetic field. Thus, the moment produced is in the opposite direction to the field and the susceptibility is negative. This effect is weak but independent of temperature. A substance whose only magnetic response is diamagnetism is called a diamagnet.
Paramagnetism Paramagnetism is a weak positive response to a magnetic field due to rotation of electron spins. Paramagnetism occurs in certain kinds of iron-bearing minerals because the iron contains an unpaired electron in one of their shells (see Hund's rules). Some are paramagnetic down to absolute zero and their susceptibility is inversely proportional to the temperature (see Curie's law); others are magnetically ordered below a critical temperature and the susceptibility increases as it approaches that temperature (see Curie–Weiss law).
Ferromagnetism
Collectively, strongly magnetic materials are often referred to as ferromagnets. However, this magnetism can arise as the result of more than one kind of magnetic order. In the strict sense, ferromagnetism refers to magnetic ordering where neighboring electron spins are aligned by the exchange interaction. The classic ferromagnet is iron. Below a critical temperature called the Curie temperature, ferromagnets have a spontaneous magnetization and there is hysteresis in their response to a changing magnetic field. Most importantly for rock magnetism, they have remanence, so they can record the Earth's field. Iron does not occur widely in its pure form. It is usually incorporated into iron oxides, oxyhydroxides and sulfides. In these compounds, the iron atoms are not close enough for direct exchange, so they are coupled by indirect exchange or superexchange. The result is that the crystal lattice is divided into two or more sublattices with different moments.
Ferrimagnetism
Ferrimagnets have two sublattices with opposing moments. One sublattice has a larger moment, so there is a net unbalance. Magnetite, the most important of the magnetic minerals, is a ferrimagnet. Ferrimagnets often behave like ferromagnets, but the temperature dependence of their spontaneous magnetization can be quite different. Louis Néel identified four types of temperature dependence, one of which involves a reversal of the magnetization. This phenomenon played a role in controversies over marine magnetic anomalies.
Antiferromagnetism
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