Rubidium hydrogen sulfate, sometimes referred to as rubidium bisulfate, is the half neutralized rubidium salt of sulfuric acid. It has the formula RbHSO4.
Properties It is a hygroscopic compound. Its crystals are isomorphs with ammonium hydrogen sulfate crystals. Its enthalpy of solution is 15.62 kJ/mol. After warming up it decomposes to rubidium disulfate and water:
2 RbHSO4 → Rb2S2O7 + H2O
Synthesis It may be synthesised with water and a stoichiometric amount of rubidium disulfate. Reaction takes place where there is no humidity:
Rb2S2O7 + H2O → 2 RbHSO4 There is another method of creation. It is similar to the synthesis of sodium sulfate and potassium sulfate. This reaction requires rubidium chloride and a little bit of warm sulfuric acid. Some hydrogen chloride is also produced during the reaction.
H2SO4 + RbCl → RbHSO4 + HCl
Related compounds Like potassium and caesium, rubidium has another hydrogen sulfate compound as well: Rb3H(SO4)2.
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