Salt water chlorination is a process that uses dissolved salt (1000–4000 ppm or 1–4 g/L) for the chlorination of swimming pools and hot tubs. The chlorine generator (also known as salt cell, salt generator, salt chlorinator, or SWG) uses electrolysis in the presence of dissolved salt to produce chlorine gas or its dissolved forms, hypochlorous acid and sodium hypochlorite, which are already commonly used as sanitizing agents in pools. Hydrogen is produced as a byproduct too.
Distinction from traditional pool chlorination The presence of chlorine in traditional swimming pools can be described as a combination of free available chlorine (FAC) and combined available chlorine (CAC). While FAC is composed of the free chlorine that is available for disinfecting the water, the CAC includes chloramines, which are formed by the reaction of FAC with amines (introduced into the pool by human perspiration, saliva, mucus, urine, and other biologics, and by insects and other pests). Chloramines are responsible for the "chlorine smell" of pools, as well as skin and eye irritation. These problems are the result of insufficient levels of free available chlorine, and indicate a pool that must be "shocked" by the addition of 5–10 times the normal amount of chlorine. In saltwater pools, the generator uses electrolysis to continuously produce free chlorine. As such, a saltwater pool or hot tub is not actually chlorine-free; it simply utilizes added salt and a chlorine generator instead of direct addition of chlorine. It also burns off chloramines in the same manner as traditional shock (oxidizer). As with traditionally chlorinated pools, saltwater pools must be monitored in order to maintain proper water chemistry. Low chlorine levels can be caused by insufficient salt, incorrect (low) chlorine-generation setting on the SWG unit, higher-than-normal chlorine demand, low stabilizer, sun exposure, insufficient pump speed, or mechanical issues with the chlorine generator. Salt count can be lowered due to splash-out, backwashing, and dilution via rainwater.
Health concerns Research has shown that because saltwater pools still use chlorine sanitization, they generate the same disinfection byproducts (DBPs) that are present in traditional pools. Of highest concern are haloketones and trihalomethanes (THMs) of those the predominant form being bromoform. Very high levels of bromoform—up to 1.3 mg per liter, or 13 times the World Health Organization's guideline values—have been found in some public saltwater swimming pools. Manufacturers have been producing saltwater chlorine generators in the United States since the early 1980s, and they first appeared commercially in New Zealand in the early 1970s (the Aquatech IG4500).
Operation The chlorinator cell consists of parallel titanium plates coated with ruthenium and sometimes iridium. Older models make use of perforated (or mesh) plates rather than solid plates. Electrolysis naturally attracts calcium and other minerals to the plates. Thus, depending on water chemistry and magnitude of use, the cell will require periodic cleaning in a mild acid solution (1 part HCl to 15 parts water) which will remove the buildup of calcium compound crystals, such as calcium carbonate or calcium nitrate. Excessive buildup can reduce the effectiveness of the cell. Running the chlorinator for long periods with insufficient salt in the pool can strip the coating off the cell which then requires an expensive replacement, as can using too strong an acid wash. Saltwater pools can also require stabilizer (cyanuric acid) to help stop the sun's UV rays from breaking down free chlorine in the pool. Usual levels are 20–50 ppm. They also require the pH to be kept between 7.2 and 7.8 with the chlorine being more effective if the pH is kept closer to 7.2. The average salt levels are usually in the 3000-5000 ppm range, much less than the ocean, which has salt levels of around 35,000 ppm. In swimming pools, salt is typically poured across the bottom and swept with the pool brush until it dissolves; if concentrated brine is allowed into the return-water system it can cause the chlorinator cell to malfunction due to overconductivity. Salt water chlorination produces an excess of hydroxide ions, and this requires the frequent addition of hydrochloric acid (HCl, also known as muriatic acid) to maintain pH.
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