Samarium(III) iodide is an inorganic compound, a salt of samarium and hydroiodic acid with the chemical formula SmI3.
Synthesis Samarium(III) iodide is prepared by the reaction of metallic samarium and iodine:
2 Sm + 3 I2 → 2 SmI3
Properties Samarium(III) iodide is a yellow powder that is unstable in air and decomposes in water (hydrolysis). When heated with metallic samarium, it forms samarium diiodide:
2SmI3 + Sm → 3 SmI2 Reduction by hydrogen also affords samarium diiodide upon heating:
2 SmI3 + H2 → 2 SmI2 + 2 HI
Applications The compound is commercially available and used in organic reactions as a catalyst.
References
