Samarium disilicide is a binary inorganic compound of samarium and silicon with the chemical formula SmSi2.
Synthesis SmSi2 is prepared by reducing samarium oxide with silicon in vacuum at 1550-1600 °C.
Physical properties Samarium disilicide exists in two crystalline modifications: α-SmSi2 and β-SmSi2, with lattices of the YSi2 orthorhombic (space group I mma) and ThSi2 tetragonal (space group I41/amd.) types respectively and a transformation temperature of 380 °C. The compound melts congruently at a temperature of ≈1800 °C.
References
