Scandium trifluoromethanesulfonate, commonly called scandium triflate, is the inorganic compound with formula Sc(H2O)8(OTf)3 where OTf is the anion CF3SO3-. It is a salt consisting of scandium aquo complex. The structure of the anhydrous derivative is less certain. Like almost all scandium compounds, this salt is colorless.
Syntheses and structure The compound is prepared by reaction of scandium oxide with trifluoromethanesulfonic acid. Concentration of these solution gives crystals of the octahydrate salt. According to X-ray crystallography, the octahydrate features a square antiprismatic cation. The hydrated salt can be dehydrated to give anhydrous derivative.
Use in organic synthesis Scandium triflate is used as a reagent in organic chemistry as a Lewis acid. Compared to other Lewis acids, this reagent is stable towards water and has been used to catalyze organic reactions. An example of the scientific use of scandium triflate is the Mukaiyama aldol addition reaction between benzaldehyde and the silyl enol ether of cyclohexanone with an 81% yield.
See also Lanthanide trifluoromethanesulfonates
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