Seleninyl chloride is the inorganic compound with the formula SeOCl2. It is a colorless liquid. With a high dielectric constant (55) and high specific conductance, it is an attractive solvent. Structurally, it is a close chemical relative of thionyl chloride SOCl2, being a pyramidal molecule.
Preparation and reactions Seleninyl chloride can be prepared by several methods, and a common one involves the conversion of selenium dioxide to dichloroselenious acid followed by dehydration:
SeO2 + 2 HCl → Se(OH)2Cl2 Se(OH)2Cl2 → SeOCl2 + H2O The original synthesis involved the redistribution reaction of selenium dioxide and selenium tetrachloride. Pure seleninyl chloride autoionizes to a dimer:
SeOCl2 ↔ (SeO)2Cl+3 + Cl− The SeOCl2 is generally a labile Lewis acid and solutions of sulfur trioxide in SeOCl2 likely form [SeOCl]+[SO3Cl]− the same way. The compound hydrolyzes readily to form hydrogen chloride and selenium dioxide, and very few organic compounds dissolve in it without reaction. At elevated temperatures, it is a strong oxidizer, yielding a chloride, selenium dioxide, and diselenium dichloride.
See also Seleninyl bromide (SeOBr2) Selenous acid (H2SeO3)
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