A selenophosphate is a chemical compound containing phosphate anions substituted with selenium. Over 7000 compounds are known with a bond between selenium and phosphorus. Compared to phosphorus-sulfur compounds selenophosphates are less thermally stable, and more easily destroyed by water. However they are more stable than tellurophosphates which have an even weaker phosphorus-tellurium bond. Selenophosphates have an oxidation number for phosphorus of +5. But in many there are bonds between phosphorus atoms, reducing the oxidation state to +4, Some may be termed selenophosphites. Different structural anions include hexaselenohypodiphosphate [P2Se6]4− and [P6Se12]4− with decalin structure and [P4Se2]2− with dicyclobutane structure. Selenophosphates are coloured, often orange. They are semiconductors. The first selenodiphosphate was discovered in 1973 by H. Hahn. Selenophosphate compounds may have some or all of the selenium replaced by sulfur.
Formation Selenophosphates can be produced by melting phosphorus selenide with metal selenides.
Molecular biology Selenocysteine is produced in many organisms from a selenophosphate. In humans and other eucaryotes, this is facilitated by the enzyme selenophosphate synthetase 1. Selenium is connected to phosphorus using a reaction with selenide and adenosine triphosphate
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References
Extra reading Wang, Fengmei; Shifa, Tofik A.; Yu, Peng; He, Peng; Liu, Yang; Wang, Feng; Wang, Zhenxing; Zhan, Xueying; Lou, Xiaoding; Xia, Fan; He, Jun (September 2018). "New Frontiers on van der Waals Layered Metal Phosphorous Trichalcogenides". Advanced Functional Materials. 28 (37) 1802151. Bibcode:2018AdvFM..2802151W. doi:10.1002/adfm.201802151. hdl:10278/3742841. ISSN 1616-301X. S2CID 105564142. Samal, Rutuparna; Sanyal, Gopal; Chakraborty, Brahmananda; Rout, Chandra Sekhar (2021). "Two-dimensional transition metal phosphorous trichalcogenides (MPX 3 ): a review on emerging trends, current state and future perspectives". Journal of Materials Chemistry A. 9 (5): 2560–2591. doi:10.1039/D0TA09752G. ISSN 2050-7488. S2CID 233958469. Susner, Michael A.; Chyasnavichyus, Marius; McGuire, Michael A.; Ganesh, Panchapakesan; Maksymovych, Petro (October 2017). "Metal Thio- and Selenophosphates as Multifunctional van der Waals Layered Materials". Advanced Materials. 29 (38) 1602852. Bibcode:2017AdM....2902852S. doi:10.1002/adma.201602852. ISSN 0935-9648. OSTI 1842642. PMID 28833546. S2CID 31497995. Chen, Zi-Xia; Liu, Wenlong; Guo, Sheng-Ping (January 2023). "A review of structures and physical properties of rare earth chalcophosphates". Coordination Chemistry Reviews. 474 214870. doi:10.1016/j.ccr.2022.214870. S2CID 252869394. Li, Zhuang; Yao, Jiyong; Wu, Yicheng (4 November 2020). "Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials". Crystal Growth & Design. 20 (11): 7550–7564. Bibcode:2020CrGrD..20.7550L. doi:10.1021/acs.cgd.0c01234. S2CID 226340520.
