A silazane is a family of compounds with Si-N bonds. Usually the Si and N have organic substituents. They are analogous to siloxanes, with -NR- (R = alkyl, aryl) replacing -O-.
Examples One illustrative family of silazanes are derived from tert-butylamine, including (CH3)3SiN(H)tBu and (CH3)2Si(N(H)tBu)2. More structurally complex is [CH3SiN(H)tBu]2(μ-N(H)tBu)2 with bridging amides. There are a wide variety of polysilazanes.
Reactions The majority of silazanes are moisture sensitive. With water they convert to silanols or siloxanes.
See also Phosphazene Paraformaldehyde
References

![Silazane: Structure of the silazane (Me3SiN)3(SiMe2)3.[1]](https://upload.wikimedia.org/wikipedia/commons/thumb/9/9b/CSD_CIF_HMMSAZ.png/500px-CSD_CIF_HMMSAZ.png?utm_source=en.wikipedia.org&utm_campaign=parser&utm_content=thumbnail)
