Silver dichromate is a chemical compound with the formula Ag2Cr2O7. It is insoluble in water and decomposes when treated with hot water. Its anion has a charge of -2.
Synthesis Silver dichromate can be precipitated by reacting potassium dichromate with silver nitrate:
K2Cr2O7 + 2 AgNO3 → Ag2Cr2O7 + 2 KNO3 Nanostructures can be produced via a sonochemical method using silver salicylate and ammonium dichromate as precursors.
Applications Related complexes are used as oxidants in organic chemistry. For instance, tetrakis(pyridine)silver dichromate, [Ag2(py)4]2+[Cr2O7]2−, is used to convert benzylic and allylic alcohols to corresponding carbonyl compounds. Dichromate solutions containing silver ions have been investigated for use in dosimetry.
References
General references Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. doi:10.1016/C2009-0-30414-6. ISBN 978-0-08-037941-8.


