Silver perrhenate is a chemical compound with the formula AgReO4. It is isostructural with the mineral scheelite (CaWO4).
Properties Silver perrhenate is soluble in O-donor and N-donor solvents as well as aromatic hydrocarbons. It forms solvates with acetonitrile and pyridine, adducts with triphenylphosphine, and 2,2′-Bipyridine.
Preparation Silver perrhenate can be precipitated by combining rhenium heptoxide and silver nitrate solutions.
Reactions Silver perrhenate reacts with trimethylsilyl chloride to give the silyl "ester" (CH3)3SiOReO3. It reacts with boron trichloride to form rhenium oxytetrachloride.
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