Silver telluride (Ag2Te) is a chemical compound, a telluride of silver, also known as disilver telluride or silver(I) telluride. It forms a monoclinic crystal. In a wider sense, silver telluride can be used to denote AgTe (silver(II) telluride, a metastable compound) or Ag5Te3.
Properties
Silver telluride is a semiconductor which can be doped both n-type and p-type. Stoichiometric Ag2Te has n-type conductivity. On heating silver is lost from the material. Non-stoichiometric silver telluride has shown extraordinary magnetoresistance.
Occurrence Silver(I) telluride occurs naturally as the mineral hessite, whereas silver(II) telluride is known as empressite. A silver gold telluride occurs as sylvanite.
Synthesis Porous silver telluride (AgTe) is synthesized by an electrochemical deposition method. A potentiostat and a three-electrode cell with sulfuric acid electrolyte containing Ag nanoparticles at are used. A silver paste used in the tungsten ditelluride (WTe2) attachment leaches into the electrolyte, causing Ag to dissolve in the electrolyte. The electrolyte is stirred to remove hydrogen bubbles. A silver-silver chloride electrode and a platinum wire can be used as reference and counter electrodes. In order to grow the porous AgTe, the WTe2 is treated with cyclic voltammetry. Glutathione-coated Ag2Te nanoparticles can be synthesized by preparing a solution containing AgNO3, Na2TeO3, and glutathione. N2H4 is added under stirring in an ice bath. The resulting product is washed for purification.
References
General references Aliev, F. F. (2002). "Phase Transition of Ag_Enriched Ag2Te". Inorganic Materials. 38 (10): 995–997. doi:10.1023/A:1020512918319. S2CID 91815176. Chuprakov, I. S.; Dahmen, K. H. (1998). "Large positive magnetoresistance in thin films of silver telluride". Applied Physics Letters. 72 (17): 2165. Bibcode:1998ApPhL..72.2165C. doi:10.1063/1.121309. Dalven, Richard (1966). "Fundamental Optical Absorption in β-Silver Telluride". Physical Review Letters. 16 (8): 311. Bibcode:1966PhRvL..16..311D. doi:10.1103/PhysRevLett.16.311. Hagyeong Kwon, Dongyeon Bae, Dongyeun Won, Heeju Kim, Gunn Kim, Jiung Cho, Hee Jung Park, Hionsuck Baik, Ah Reum Jeong, Chia-Hsien Lin, Ching-Yu Chiang, Ching-Shun Ku, Heejun Yang, and Suyeon Cho "Nanoporous Silver Telluride for active hydrogen evolution." (n.d.) https://pubs.acs.org/doi/10.1021/acsnano.0c09517


