Smoke is an aerosol (a suspension of particulates in gases) emitted when a material undergoes combustion or pyrolysis, together with the quantity of air that is entrained or otherwise mixed into the mass. It is commonly an unwanted by-product of fires (including stoves, candles, internal combustion engines, oil lamps, and fireplaces), but may also be used for pest control (fumigation), communication (smoke signals), defensive and offensive capabilities in the military (smoke screen), cooking, or smoking (tobacco, cannabis, etc.). It is used in rituals where incense, sage, or resin is burned to produce a smell for spiritual or magical purposes. It can also be a flavoring agent and preservative. Smoke inhalation is the primary cause of death in victims of indoor fires. The smoke kills by a combination of thermal damage, poisoning and pulmonary irritation caused by carbon monoxide, hydrogen cyanide and other combustion products. Smoke is an aerosol (or mist) of solid particles and liquid droplets that are close to the ideal range of sizes for Mie scattering of visible light.
Chemical composition
The composition of smoke depends on the nature of the burning fuel and the conditions of combustion. Fires with high availability of oxygen burn at a high temperature and with a small amount of smoke produced; the particles are mostly composed of ash, or with large temperature differences, of condensed aerosol of water. High temperature also leads to production of nitrogen oxides. Sulfur content yields sulfur dioxide, or in case of incomplete combustion, hydrogen sulfide. Carbon and hydrogen are almost completely oxidized to carbon dioxide and water. Fires burning with lack of oxygen produce a significantly wider palette of compounds, many of them toxic. Partial oxidation of carbon produces carbon monoxide, while nitrogen-containing materials can yield hydrogen cyanide, ammonia, and nitrogen oxides. Hydrogen gas can be produced instead of water. Contents of halogens such as chlorine (e.g. in polyvinyl chloride or brominated flame retardants) may lead to the production of hydrogen chloride, phosgene, dioxin, and chloromethane, bromomethane and other halocarbons. Hydrogen fluoride can be formed from fluorocarbons, whether fluoropolymers subjected to fire or halocarbon fire suppression agents. Phosphorus and antimony oxides and their reaction products can be formed from some fire retardant additives, increasing smoke toxicity and corrosivity. Pyrolysis of polychlorinated biphenyls (PCB), e.g. from burning older transformer oil, and to lower degree also of other chlorine-containing materials, can produce 2,3,7,8-tetrachlorodibenzodioxin, a potent carcinogen, and other polychlorinated dibenzodioxins. Pyrolysis of fluoropolymers, e.g. teflon, in presence of oxygen yields carbonyl fluoride (which hydrolyzes readily to HF and CO2); other compounds may be formed as well, e.g. carbon tetrafluoride, hexafluoropropylene, and highly toxic perfluoroisobutene (PFIB).
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![Smoke: Chemical composition distribution of volatile organic compounds released in smoke from a variety of solid fuels[4]](https://upload.wikimedia.org/wikipedia/commons/thumb/5/55/Smoke_chemical_composition.jpg/500px-Smoke_chemical_composition.jpg?utm_source=en.wikipedia.org&utm_campaign=parser&utm_content=thumbnail)



