Sodium cyanate is the inorganic compound with the formula NaOCN. A white solid, it is the sodium salt of the cyanate anion.
Structure The anion is described by two resonance structures: N≡C−O− and −N=C=O The salt adopts a body centered rhombohedral crystal lattice structure (trigonal crystal system) at room temperature.
Preparation Sodium cyanate is prepared industrially by the reaction of urea with sodium carbonate at elevated temperature.
2OC(NH2)2 + Na2CO3 → 2Na(NCO) + CO2 + 2NH3 + H2O Sodium allophanate is observed as an intermediate:
H2NC(O)NHCO2Na → NaOCN + NH3 + CO2 It can also be prepared in the laboratory by oxidation of a cyanide in aqueous solution by a mild oxidizing agent such as lead oxide.
Uses and reactions The main use of sodium cyanate is for steel hardening. Sodium cyanate is used to produce cyanic acid, often in situ:
NaOCN + HCl → HOCN + NaCl This approach is exploited for condensation with amines to give unsymmetrical ureas:
HOCN + RNH2 → RNHC(O)NH2 Such urea derivatives have a range of biological activity.
See also Cyanate
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