Sodium diethyldiselenocarbamate is the organoselenium compound with the formula (CH3CH2)2NCSe−2Na+. It is a deep yellow, water soluble salt. It is one of the best studied diselenocarbamates, otherwise a rare class of compounds.
Preparation and reactions Sodium diethyldiselenocarbamate is obtained by treating carbon diselenide with diethylamine in the presence of sodium hydroxide:
CSe2 + HN(C2H5)2 + NaOH → NaSe2CN(C2H5)2 + H2O Other diselenocarbamates can be prepared similarly from secondary amines and carbon diselenide. The related diselenoxanthates have also been prepared. Diethyldiselenocarbamate forms coordination complexes with many transition metals. With Se(II), it forms the bicyclic Se(Se2CN(C2H5)2)2.
Structure and bonding The C2NCSe2 core of the diethyldiselenocarbamate anion and its complexes is planar, indicating some C–N multiple bond character.
See also Sodium diethyldithiocarbamate Transition metal dithiocarbamate complexes
References


