Sodium hexafluoroantimonate is an inorganic chemical compound with the chemical formula NaSbF6.
Synthesis Sodium hexafluoroantimonate may be synthesised by oxidation of antimony trioxide with bromine trifluoride:
6Sb2O3 + 20BrF3 + 12NaF → 12Na[SbF6] + 10Br2 + 9O2 Or it may be formed by reaction of antimony and sodium fluorides:
SbF5 + NaF → Na[SbF6]
Physical properties Sodium hexafluoroantimonate forms colorless crystals, soluble in water. It crystallizes in the cubic Pa3 space group with unit cell dimension of a=0.820 Å.
Chemical properties Sodium hexafluoroantimonate undergoes slow partial hydrolysis in aqueous solutions.
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