Sodium maleonitriledithiolate is the chemical compound described by the formula Na2S2C2(CN)2. The name refers to the cis compound, structurally related to maleonitrile ((CH(CN))2). Maleonitriledithiolate is often abbreviated mnt. It is a "dithiolene", i.e. a chelating alkene-1,2-dithiolate. It is a prototypical non-innocent ligand in coordination chemistry. Several complexes are known, such as Ni(mnt)2]2−.
The salt is synthesized by treating carbon disulfide with sodium cyanide to give the cyanodithioformate salt, which eliminates elemental sulfur in aqueous solution:
8 NaCN + 8 CS2 → 4 Na2S2C2(CN)2 + S8 The compound was first described in 1958.
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![Sodium maleonitriledithiolate: Sample of ([(CH3CH2)4N]+)2[Ni(mnt)2]2−.](https://upload.wikimedia.org/wikipedia/commons/thumb/2/2b/%28Et4N%292Ni%28mnt%292.jpg/1280px-%28Et4N%292Ni%28mnt%292.jpg?utm_source=en.wikipedia.org&utm_campaign=parser&utm_content=thumbnail)
