Sodium tetracarbonylcobaltate is the organocobalt compound with the formula NaCo(CO)4. It is a common derivative of the tetracarbonylcobaltate anion, [Co(CO)4]-, although several other alkali metal salts are known. The tetracarbonylcobaltate anion is the conjugate base of cobalt tetracarbonyl hydride, HCo(CO)4. According to X-ray crystallography, the Co(CO)4- center is nearly tetrahedral (isoelectronic with Ni(CO)4). Conventionally, this compound is prepared by reduction of dicobalt octacarbonyl with sodium amalgam:
Co2(CO)8 + 2 Na → 2 NaCo(CO)4 It reacts with mercuric cyanide to give a HgCo2 derivative:
Hg(CN)2 + 2 NaCo(CO)4 → Hg[Co(CO)4]2 + 2 NaCN
References





