Solder is a metallic material that is used to connect metal workpieces. The choice of specific solder alloys depends on their melting point, chemical reactivity, mechanical properties, toxicity, and other properties. Hence a wide range of solder alloys exist, and only major ones are listed below. Since early 2000s the use of lead in solder alloys is discouraged by several governmental guidelines in the European Union, Japan and other countries, such as Restriction of Hazardous Substances Directive and Waste Electrical and Electronic Equipment Directive. Despite regulatory encouragement, the industry transition to lead-free solders has encountered technical challenges related to process compatibility, alloy reliability, and solder joint microstructure that have required extensive study and adaptation.
Solder alloys Note: the subscripts in the composition are mass percentages, not atom/molar ratios.
Notes on the above table In the Sn-Pb alloys, tensile strength increases with increasing tin content. Indium-tin alloys with high indium content have very low tensile strength. For soldering semiconductor materials, e.g. die attachment of silicon, germanium and gallium arsenide, it is important that the solder contains no impurities that could cause doping in the wrong direction. For soldering n-type semiconductors, solder may be doped with antimony (group V); indium (group III) may be added for soldering p-type semiconductors. Most semiconductor solders in practical use are made wholly of elements without a doping effect such as Ph, Sn, Ag, Au, Cu. The use of tin-based lead-free solder carries risks of tin whisker, and intermetallic compound growth (tin pest is however not a common issue due to alloying). Various fusible alloys can be used as solders with very low melting points; examples include Field's metal (In51Bi31.5Sn16.5), Lipowitz's alloy, Wood's metal (Bi50Pb26.7Sn13.3Cd10), and Rose's metal (Bi50Pb50Sn50).
Properties The thermal conductivity of common solders ranges from 30 to 400 W/(m·K), and the density from 9.25 to 15.00 g/cm3.
References
External links
Phase diagrams of different types of solder alloys


