During nuclear magnetic resonance observations, spin–lattice relaxation is the mechanism by which the longitudinal component of the total nuclear magnetic moment vector (parallel to the constant magnetic field) exponentially relaxes from a higher energy, non-equilibrium state to thermodynamic equilibrium with its surroundings (the "lattice"). It is characterized by the spin–lattice relaxation time, a time constant known as T 1 {\displaystyle T_{1}} . There is a different parameter, T 2 {\displaystyle T_{2}} , the spin–spin relaxation time, which concerns the exponential relaxation of the transverse component of the nuclear magnetization vector (perpendicular to the external magnetic field). Measuring the variation of T 1 {\displaystyle T_{1}} and T 2 {\displaystyle T_{2}} in different materials is the basis for some magnetic resonance imaging techniques.
Nuclear physics
The rate at which the longitudinal M z {\displaystyle M_{z}} component of the magnetization vector recovers exponentially towards its thermodynamic equilibrium is governed by the time T 1 {\displaystyle T_{1}} , according to equation
M z ( t ) = M z , e q − [ M z , e q − M z ( 0 ) ] e − t / T 1 , {\displaystyle M_{z}(t)=M_{z,\mathrm {eq} }-\left[M_{z,\mathrm {eq} }-M_{z}(0)\right]e^{-t/T_{1}},} or, for the specific case that M z ( 0 ) = − M z , e q {\displaystyle M_{z}(0)=-M_{z,\mathrm {eq} }} ,
M z ( t ) = M z , e q ( 1 − 2 e − t / T 1 ) . {\displaystyle M_{z}(t)=M_{z,\mathrm {eq} }\left(1-2e^{-t/T_{1}}\right).}
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