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Spinning (polymers)

Spinning (polymers) is a chemistry topic covered in the lgStudy science library. This page brings together a partial reference excerpt, illustrations, worked examples, real-world applications and a short study plan, so you can understand Spinning (polymers) rather than just read about it. In short: Spinning is a manufacturing process for creating polymer fibers. It is a specialized form of extrusion that uses a spinneret to form multiple continuous filaments.

Key takeaways

  • Spinning (polymers) belongs to chemistry; place it in that map before memorising details.
  • Learn the definition first, then one example that makes the definition concrete.
  • Connect Spinning (polymers) to a quantity you can measure, compute or draw — that is where exam questions come from.
  • Reproduce the core statement of Spinning (polymers) from memory before moving on to harder problems.

Reference excerpt

Spinning is a manufacturing process for creating polymer fibers. It is a specialized form of extrusion that uses a spinneret to form multiple continuous filaments.

Melt spinning If the polymer is a thermoplastic then it can undergo melt spinning. The molten polymer is extruded through a spinneret composed of capillaries where the resulting filament is solidified by cooling. Nylon, olefin, polyester, saran, and sulfar are produced via this process.

Extrusion spinning Pellets or granules of the solid polymer are fed into an extruder. The pellets are compressed, heated and melted by an extrusion screw, then fed to a spinning pump and into the spinneret.

Direct spinning The direct spinning process avoids the stage of solid polymer pellets. The polymer melt is produced from the raw materials, and then from the polymer finisher directly pumped to the spinning mill. Direct spinning is mainly applied during production of polyester fibers and filaments and is dedicated to high production capacity (>100 ton/day).

Solution spinning If the melting point of the polymer is higher than its degradation temperature, the polymer must undergo solution spinning techniques for fiber formation. The polymer is first dissolved in a solvent, forming a spinning solution (sometimes called a "dope"). The spinning solution then undergoes dry, wet, dry-jet wet, gel, or electrospinning techniques.

Dry spinning A spinning solution consisting of polymer and a volatile solvent is extruded through a spinneret into an evaporating chamber. A stream of hot air impinges on the jets of spinning solution emerging from the spinneret, evaporating the solvent, and solidifying the filaments. Solution blow spinning is a similar technique where polymer solution is sprayed directly onto a target to produce a nonwoven fiber mat.

Wet spinning Wet spinning is the oldest of the five processes. The polymer is dissolved in a spinning solvent where it is extruded out through a spinneret submerged in a coagulation bath composed of nonsolvents. The coagulation bath causes the polymer to precipitate in fiber form. Acrylic, rayon, aramid, modacrylic, and spandex are produced via this process. A variant of wet spinning is dry-jet wet spinning, where the spinning solution passes through an air-gap prior to being submerged into the coagulation bath. This method is used in Lyocell spinning of dissolved cellulose, and can lead to higher polymer orientation due to the higher stretchability of the spinning solution versus the precipitated fiber.

Gel spinning Gel spinning, also known as semi-melt spinning, is used to obtain high strength or other special properties in the fibers. Instead of wet spinning, which relies on precipitation as the main mechanism for solidification, gel spinning relies on temperature-induced physical gelation as the primary method for solidification. The resulting gelled fiber is then swollen with the spinning solvent (similar to gelatin desserts) which keeps the polymer chains somewhat bound together, resisting relaxation which is prevalent in wet spinning. The high solvent retention allows for ultra-high drawing as with ultra high molecular weight polyethylene (UHMWPE) (e.g., Spectra®) to produce fibers with a high degree of orientation, which increases fiber strength. The fibers are first cooled either with air or in a liquid bath to induce gelation, then the solvent is removed through ageing in a nonsolvent, or during the drawing stage. Some high strength polyethylene and polyacrylonitrile fibers are produced via this process.

Electrospinning

Electrospinning uses an electrical charge to draw very fine (typically on the micro or nano scale) fibres from a liquid - either a polymer solution or a polymer melt. Electrospinning shares characteristics of both electrospraying and conventional solution dry spinning of fibers. The process does not require the use of coagulation chemistry or high temperatures to produce solid threads from solution. This makes the process particularly suited to the production of fibers using large and complex molecules. Melt electrospinning is also practiced; this method ensures that no solvent can be carried over into the final product.

Post-spin processes

Drawing

Finally, the fibers are drawn to increase strength and orientation. This may be done while the polymer is still solidifying or after it has completely cooled.

See also Spinneret (polymers)

References

Worked examples

Example 1 — a first encounter with Spinning (polymers)

Start with the simplest possible case. Write down what Spinning (polymers) claims or describes in one sentence, then invent the smallest concrete situation in which that sentence is true. In chemistry, the smallest case is usually a single object, a single equation or a single measurement. Check that every symbol or term in your sentence has a meaning in that case.

Example 2 — changing one variable

Take the situation from Example 1 and change exactly one quantity: double it, halve it, or set it to zero. Predict what should happen to Spinning (polymers) before you calculate. Comparing your prediction with the result is the fastest way to find out whether you understand the idea or only the words.

Example 3 — an exam-style question

Typical questions about Spinning (polymers) ask you to (a) state it precisely, (b) apply it to given data, and (c) explain a limitation. Practise writing all three answers in under five minutes; the third part is what separates a full-mark answer from an average one.

Applications of Spinning (polymers)

In research
Spinning (polymers) appears in chemistry research whenever the underlying quantities have to be modelled precisely. Papers usually cite it as a starting assumption and then explore where it breaks down.
In technology and industry
Engineering practice reuses Spinning (polymers) in design rules, simulations and safety margins. Knowing the idea lets you read a specification sheet and understand why the numbers look the way they do.
In the classroom
Spinning (polymers) is common in secondary-school and first-year university syllabi. It links to neighbouring topics Plastics industry, Synthetic fibers, Textile engineering, so understanding it makes those chapters shorter.
In everyday life
Look for Spinning (polymers) outside the textbook — in sport, cooking, traffic, electronics or the sky above you. An example you found yourself is remembered far longer than one you were given.
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How to study Spinning (polymers) in 20 minutes

  1. Read the reference excerpt below once, without taking notes.
  2. Close the page and write down what Spinning (polymers) means in your own words.
  3. Compare your version with the excerpt and mark what you missed.
  4. Work through the three examples above with pen and paper.
  5. Explain Spinning (polymers) out loud to somebody else — or to Teacher Smith in the lgStudy chat.

Frequently asked questions

What is Spinning (polymers) in simple terms?

Spinning is a manufacturing process for creating polymer fibers. It is a specialized form of extrusion that uses a spinneret to form multiple continuous filaments.

Why does Spinning (polymers) matter?

Because it connects several chemistry ideas at once: it gives you a definition you can apply, a quantity you can calculate, and a way to check whether a result is plausible.

How should I study Spinning (polymers)?

Read the excerpt, restate it from memory, then work through the examples and applications listed on this page. The five-step study plan above takes about twenty minutes.

What does this page cover?

It gives you a compact reference excerpt plus original lgStudy explanations, examples, applications and study material on Spinning (polymers).

Tags

  • Plastics industry
  • Synthetic fibers
  • Textile engineering

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