Stannane or tin hydride is an inorganic compound with the chemical formula SnH4. It is a colourless gas that ignites on contact with air. SnH4 is a heavy analogue of methane but much less robust. In contrast to this rarely used species, stannane also refers to a large collection of organotin compounds.
Preparation and reactions Stannane can be prepared by the reaction of SnCl4 and lithium aluminium hydride according to the following idealized equation:
SnCl4 + Li[AlH4] → SnH4 + LiCl + AlCl3 Stannane decomposes slowly at room temperature to give metallic tin and hydrogen.
SnH4 → Sn + 2H2 Organotin hydrides are more stable, e.g. triphenyltin hydride, also known as triphenylstannane.
Occurrence in industry The volatility of stannane is potentially relevant to production of microchips.
See also Organotin
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