The Stefan–Boltzmann law, also known as Stefan's law, describes the intensity of the thermal radiation emitted by matter in terms of that matter's temperature. It is named for Josef Stefan, who empirically derived the relationship, and Ludwig Boltzmann who derived the law theoretically. For an ideal absorber/emitter or black body, the Stefan–Boltzmann law states that the total energy radiated per unit surface area per unit time (also known as the radiant exitance) is directly proportional to the fourth power of the black body's temperature, T {\displaystyle T} :
M ∘ = σ T 4 . {\displaystyle M^{\circ }=\sigma \,T^{4}.}
The constant of proportionality, σ {\displaystyle \sigma } , is called the Stefan–Boltzmann constant. It has the value
In the general case, the Stefan–Boltzmann law for radiant exitance takes the form:
M = ε M ∘ = ε σ T 4 , {\displaystyle M=\varepsilon \,M^{\circ }=\varepsilon \,\sigma \,T^{4},}
where ε {\displaystyle \varepsilon } is the emissivity of the surface emitting the radiation. The emissivity is generally between zero and one. An emissivity of one corresponds to a black body.
Detailed explanation The radiant exitance (previously called radiant emittance), M {\displaystyle M} , has dimensions of energy flux (energy per unit time per unit area), and the SI units of measure are joules per second per square metre (J⋅s−1⋅m−2), or equivalently, watts per square metre (W⋅m−2). The SI unit for absolute temperature, T, is the kelvin (K). To find the total power, P {\displaystyle P} , radiated from an object, multiply the radiant exitance by the object's surface area, A {\displaystyle A} :
P = A ⋅ M = A ε σ T 4 . {\displaystyle P=A\cdot M=A\,\varepsilon \,\sigma \,T^{4}.}
Matter that does not absorb all incident radiation emits less total energy than a black body. Emissions are reduced by a factor ε {\displaystyle \varepsilon } , where the emissivity, ε {\displaystyle \varepsilon } , is a material property which, for most matter, satisfies 0 ≤ ε ≤ 1 {\displaystyle 0\leq \varepsilon \leq 1} . Emissivity can in general depend on wavelength, direction, and polarization. However, the emissivity which appears in the non-directional form of the Stefan–Boltzmann law is the hemispherical total emissivity, which reflects emissions as totaled over all wavelengths, directions, and polarizations. The form of the Stefan–Boltzmann law that includes emissivity is applicable to all matter, provided that matter is in a state of local thermodynamic equilibrium (LTE) so that its temperature is well-defined. (This is a trivial conclusion, since the emissivity, ε {\displaystyle \varepsilon } , is defined to be the quantity that makes this equation valid. What is non-trivial is the proposition that ε ≤ 1 {\displaystyle \varepsilon \leq 1} , which is a consequence of Kirchhoff's law of thermal radiation.) A so-called grey body is a body for which the spectral emissivity is independent of wavelength, so that the total emissivity, ε {\displaystyle \varepsilon } , is a constant. In the more general (and realistic) case, the spectral emissivity depends on wavelength. The total emissivity, as applicable to the Stefan–Boltzmann law, may be calculated as a weighted average of the spectral emissivity, with the blackbody emission spectrum serving as the weighting function. It follows that if the spectral emissivity depends on wavelength then the total emissivity depends on the temperature, i.e., ε = ε ( T ) {\displaystyle \varepsilon =\varepsilon (T)} . However, if the dependence on wavelength is small, then the dependence on temperature will be small as well. Wavelength- and subwavelength-scale particles, metamaterials, and other nanostructures are not subject to ray-optical limits and may be designed to have an emissivity greater than 1. In national and international standards documents, the symbol M {\displaystyle M} is recommended to denote radiant exitance; a superscript circle (°) indicates a term relative to a black body. (A subscript "e" is added when it is important to distinguish the energetic (radiometric) quantity radiant exitance, M e {\displaystyle M_{\mathrm {e} }} , from the analogous human vision (photometric) quantity, luminous exitance, denoted M v {\displaystyle M_{\mathrm {v} }} .) In common usage, the symbol used for radiant exitance (often called radiant emittance) varies among different texts and in different fields. The Stefan–Boltzmann law may be expressed as a formula for radiance as a function of temperature. Radiance is measured in watts per square metre per steradian (W⋅m−2⋅sr−1). The Stefan–Boltzmann law for the radiance of a black body is:
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