Sulfur trifluoride is the inorganic chemical compound with the formula SF3. It is a radical.
Structure and synthesis Sulfur trifluoride is predicted to be pyramidal. SF3 is generated by irradiation of crystals of trifluorosulfonium tetrafluoroborate [SF3]+[BF4]− with gamma rays.
SF−3 A derivative formally derived from SF−3 is the coordination complex Ir(Cl)(CO)(F)(SF3)(Et3P)2 obtained by oxidative addition of sulfur tetrafluoride to Ir(Cl)(CO)(PEt3)2 (Et = C2H5).
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