Surface tension is the energy per unit area due to having a surface in a liquid. It has the dimension of force per unit length, or energy per unit area. The two are equivalent, but when referring to energy per unit of area, it is common to use the term surface energy, which is a more general term in the sense that it applies also to solids. Surface tension is used for liquids, while surface stress and surface energy are more commonly used for solids. An example of its relevance is the tendency of liquid surfaces at rest to shrink to the minimum surface area possible. Because of the relatively high attraction of water molecules to each other through a web of hydrogen bonds, water has a higher surface tension (72.8 millinewtons (mN) per meter at 20 °C) than most other liquids. This allows objects with a higher density than water such as razor blades and insects (e.g. water striders) to float on a water surface without becoming even partly submerged. The magnitude of the surface tension is connected to the forces between the molecules at the surface. Therefore surfactants are often used to reduce it so there is more contact between the liquid and another material, for instance detergents. It can also lead to pressure inside water bubbles, as well as many other phenomena; it is a classic, well-studied property common to all liquids.
Causes
Due to the cohesive forces, a molecule located away from the surface is pulled equally in every direction by neighboring liquid molecules, resulting in a net force of zero. The molecules at the surface do not have an equal number of molecules on all sides of them and therefore are pulled inward. This creates some internal pressure and forces liquid surfaces to contract to the minimum area. There is also a tension parallel to the surface at the liquid-air interface which will resist an external force, due to the cohesive forces between the molecules. The forces of attraction acting between molecules of the same type are called cohesive forces, while those acting between molecules of different types are called adhesive forces. The balance between the cohesion of the liquid and its adhesion to the material of the container determines the degree of wetting, the contact angle, and the shape of the meniscus. When cohesion dominates (specifically, adhesion energy is less than half of cohesion energy) the wetting is low and the meniscus is convex at a vertical wall (as for mercury in a glass container). On the other hand, when adhesion dominates (when adhesion energy is more than half of cohesion energy) the wetting is high and the similar meniscus is concave (as in water in a glass). Surface tension is responsible for the shape of liquid droplets. Although easily deformed, droplets of water tend to be pulled into a spherical shape by the imbalance in cohesive forces of the surface layer. In the absence of other forces, drops of virtually all liquids would be approximately spherical. The spherical shape minimizes the necessary "wall tension" of the surface layer according to Laplace's law.
Another way to view surface tension is in terms of energy. A molecule in contact with a neighbor is in a lower state of energy than if it were alone. The interior molecules have as many neighbors as they can possibly have, but the boundary molecules are missing neighbors (compared to interior molecules) and therefore have higher energy. For the liquid to minimize its energy state, the number of higher energy boundary molecules must be minimized. The minimized number of boundary molecules results in a minimal surface area. As a result of surface area minimization, a surface will assume a smooth shape.
Physics
Physical units Surface tension, represented by the symbol γ (alternatively σ or T), is measured in force per unit length. Its SI unit is newton per metre but the cgs unit of dyne per centimetre is also used, particularly in the older literature. For example,
γ = 1 d y n c m = 1 e r g c m 2 = 1 10 − 7 m ⋅ N 10 − 4 m 2 = 0.001 N m = 0.001 J m 2 . {\displaystyle \gamma =1~\mathrm {\frac {dyn}{cm}} =1~\mathrm {\frac {erg}{cm^{2}}} =1~\mathrm {\frac {10^{-7}\,m\cdot N}{10^{-4}\,m^{2}}} =0.001~\mathrm {\frac {N}{m}} =0.001~\mathrm {\frac {J}{m^{2}}} .}
Definition
Surface tension can be defined in terms of force or energy.
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