Synthetic resin is an industrially produced, typically viscous substance that converts into rigid polymers by the process of curing. They are formed by the reaction of dibasic organic acids and polyhydric alcohols. In order to undergo curing, resins typically contain reactive groups, such as acrylates or epoxides. Some synthetic resins have properties similar to natural plant resins, but many do not. Synthetic resins are of several classes. Some are manufactured by esterification of organic compounds. Some are thermosetting plastics in which the term "resin" is loosely applied to the reactant(s), the product, or both. "Resin" may be applied to one or more monomers in a copolymer, the other being called a "hardener", as in epoxy resins. For thermosetting plastics that require only one monomer, the monomer compound is the "resin". For example, liquid methyl methacrylate is often called the "resin" or "casting resin" while in the liquid state, before it polymerizes and "sets". After setting, the resulting poly(methyl methacrylate) (PMMA) is often renamed "acrylic glass" or "acrylic" (trade names include Plexiglas and Lucite).
Uses Synthetic resins are also used extensively in cured-in-place pipe applications. Departments of transportation in the United States also specify them for use as overlays on roads and bridges. In this application, they are known as polyester concrete overlays (PCO). These are usually based on isophthalic acid and cut with styrene at high levels—usually up to 50%. Synthetic resins are also used in anchor bolt adhesives, though epoxy based materials are also used. Many companies have and continue to introduce styrene-free systems mainly due to odor issues, but also over concerns that styrene is a potential carcinogen. Drinking water applications also prefer styrene-free resins. Dental restorative materials based on bis-GMA-containing resins can break down into or be contaminated with the related compound bisphenol A, a potential endocrine disruptor. However, no negative health effects of bis-GMA use in dental resins have been found.
Types
There are a number of materials which may be described as "synthetic resin". One variety is epoxy resin, manufactured through polymerization-polyaddition or polycondensation reactions and used as a thermoset polymer for adhesives and composites. Accordingly, it has mainly seen use in industrial flooring purposes since the 1960s. Since 2000, however, epoxy and polyurethane resins are used in interiors as well, mainly in Western Europe. Synthetic "casting resin" for embedding display objects in Plexiglas/Lucite (PMMA) is simply methyl methacrylate liquid, into which a polymerization catalyst is added and mixed, causing it to "set" (polymerize). The polymerization creates a block of PMMA plastic ("acrylic glass") which holds the display object inside a transparent block. Another synthetic polymer sometimes called by the same general name is acetal resin. By contrast with the other synthetics, however, it has a simple chain structure with the repeat unit of form −[CH2O]−. Ion-exchange resins are used in water purification and catalysis of organic reactions. (See also AT-10 resin, melamine resin.) Certain ion-exchange resins are also used pharmaceutically as bile acid sequestrants, mainly as hypolipidemic agents, although they may be used for purposes other than lowering cholesterol. Solvent impregnated resins (SIRs) are porous resin particles which contain an additional liquid extractant inside the porous matrix. The contained extractant is supposed to enhance the capacity of the resin particles. The production of PVC entails the production of "vinyl chloride resins", which differ in the degree of polymerization. Silicone resins are silicone-based polymers that exhibit various useful properties like weatherability (durability), dielectricity, water repellency, thermal stability, and chemical inertness.
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