Talc, or talcum, is a clay mineral composed of hydrated magnesium silicate, with the chemical formula Mg3Si4O10(OH)2. Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thickening agent and lubricant. It is an ingredient in ceramics, paints, and roofing material. It is a main ingredient in many cosmetics. It occurs as foliated to fibrous masses, and in an exceptionally rare crystal form. It has a perfect basal cleavage and an uneven flat fracture, and it is foliated with a two-dimensional platy form. The Mohs scale of mineral hardness, based on scratch hardness comparison, defines value 1 as the hardness of talc, the softest mineral. When scraped on a streak plate, talc produces a white streak, though this indicator is of little importance, because most silicate minerals produce a white streak. Talc is translucent to opaque, with colors ranging from whitish grey to green with a vitreous and pearly luster. Talc is not soluble in water, and is slightly soluble in dilute mineral acids. Soapstone is a metamorphic rock composed predominantly of talc.
Etymology The word talc derives from Persian: تالک tālk. In ancient times, the word was used for various related minerals, including talc, mica, and selenite.
Formation
Talc dominantly forms from the metamorphism of magnesian minerals such as serpentine, pyroxene, amphibole, and olivine, in the presence of carbon dioxide and water. This is known as "talc carbonation" or "steatization" and produces a suite of rocks known as talc carbonates. Talc is primarily formed by hydration and carbonation by this reaction:
serpentine2 Mg3Si2O5(OH)4 + carbon dioxide3 CO2 → talcMg3Si4O10(OH)2 + magnesite3 MgCO3 + water3 H2O Talc can also be formed via a reaction between dolomite and silica, which is typical of skarnification of dolomites by silica-flooding in contact metamorphic aureoles:
dolomite3 CaMg(CO3)2 + silica4 SiO2 + waterH2O → talcMg3Si4O10(OH)2 + calcite3 CaCO3 + carbon dioxide3 CO2 Talc can also be formed from magnesium chlorite and quartz in blueschist and eclogite metamorphism by the following metamorphic reaction:
chlorite + quartz → kyanite + talc + water Talc is also found as a diagenetic mineral in sedimentary rocks where it can form from the transformation of metastable hydrated magnesium-clay precursors such as kerolite, sepiolite, or stevensite that can precipitate from marine and lake water in certain conditions. In this reaction, the ratio of talc and kyanite depends on aluminium content, with more aluminous rocks favoring production of kyanite. This is typically associated with high-pressure, low-temperature minerals such as phengite, garnet, and glaucophane within the lower blueschist facies. Such rocks are typically white, friable, and fibrous, and are known as whiteschist. Talc is a trioctahedral layered mineral; its structure is similar to pyrophyllite, but with magnesium in the octahedral sites of the composite layers. The crystal structure of talc is described as TOT, meaning that it is composed of parallel TOT layers weakly bonded to each other by weak van der Waals forces. The TOT layers in turn consist of two tetrahedral sheets (T) strongly bonded to the two faces of a single trioctahedral sheet (O). It is the weak bonding between TOT layers that gives talc its perfect basal cleavage and softness. The tetrahedral sheets consist of silica tetrahedra, which are silicon ions surrounded by four oxygen ions. The tetrahedra each share three of their four oxygen ions with neighboring tetrahedra to produce a hexagonal sheet. The remaining oxygen ion (the apical oxygen ion) is available to bond with the trioctahedral sheet. The trioctahedral sheet has the structure of a sheet of the mineral brucite. Apical oxygens take the place of some of the hydroxyl ions that would be present in a brucite sheet, bonding the tetrahedral sheets tightly to the trioctahedral sheet. Tetrahedral sheets have a negative charge, since their bulk composition is Si4O4−10. The trioctahedral sheet has an equal positive charge, since its bulk composition is Mg3(OH)4+2 The combined TOT layer thus is electrically neutral. Because the hexagons in the T and O sheets are slightly different in size, the sheets are slightly distorted when they bond into a TOT layer. This breaks the hexagonal symmetry and reduces it to monoclinic or triclinic symmetry. However, the original hexahedral symmetry is discernible in the pseudotrigonal character of talc crystals.
Occurrence
Talc is a common metamorphic mineral in metamorphic belts that contain ultramafic rocks, such as soapstone (a high-talc rock), and within whiteschist and blueschist metamorphic terranes. Prime examples of whiteschists include the Franciscan Metamorphic Belt of the western United States, the western European Alps especially in Italy, certain areas of the Musgrave Block, and some collisional orogens such as the Himalayas, which stretch along Pakistan, India, Nepal, and Bhutan. Talc carbonate ultramafics are typical of many areas of the Archaean cratons, notably the komatiite belts of the Yilgarn craton in Western Australia. Talc-carbonate ultramafics are also known from the Lachlan Fold Belt, eastern Australia, from Brazil, the Guiana Shield, and from the ophiolite belts of Turkey, Oman, and the Middle East. China is the key world talc and steatite-producing country with an output of about 2.2 million tonnes (2016), which accounts for 30% of total global output. The other major producers are Brazil (12%), India (11%), the U.S. (9%), France (6%), Finland (4%), Italy, Russia, Canada, and Austria (2%, each). Notable economic talc occurrences include the Mount Seabrook talc mine, Western Australia, formed upon a polydeformed, layered ultramafic intrusion. The France-based Luzenac Group is the world's largest supplier of mined talc. Its largest talc mine at Trimouns near Luzenac in southern France produces 400,000 tonnes of talc per year.
Conflict mineral Extraction in disputed areas of Nangarhar province, Afghanistan, has led the international monitoring group Global Witness to declare talc a conflict resource, as the profits are used to fund armed confrontation between the Taliban and Islamic State.
Uses
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