Terbium(III) sulfate is an inorganic compound with the chemical formula Tb2(SO4)3. It is a colorless solid, forming monoclinic crystals.
Properties
The octahydrate is isostructural with the octahydrates of praseodymium sulfate and dysprosium sulfate. It exhibits many forms of luminescence including triboluminescence, chemiluminescence (such as during the thermal degradation of sodium persulfate in the presence of terbium sulfate), and sonoluminescence (as a suspension in benzene, toluene, or p-xylene).
Preparation The octahydrate can be prepared by treating terbium(III,IV) oxide with sulfuric acid. The anhydrous form is obtained by heating to 360 °C.
Reactions Terbium oxysulfide (Tb2O2S) is obtained by heating the hydrate under a reductive CO atmosphere at 1,033 K (760 °C; 1,400 °F). If an air atmosphere is used instead, a terbium oxysulfate (Tb2O2SO4) forms at 1,323 K (1,050 °C; 1,922 °F).
Related compounds Double sulfates such as sodium terbium sulfate are formed in the separation of lanthanides by fractional precipitation, a historically employed method. A hydrogensulfate sulfate (Tb(HSO4)(SO4)) has been characterized. It is prepared by solvothermal synthesis, crystallizes in the P21 space group, and exhibits second-harmonic generation. Several terbium sulfate-based solid state materials have been characterized by single-crystal X-ray diffraction. For example, inorganic frameworks such as the 1D (H3O)2(C2H8N)[Tb(SO4)3] and 3D (C2H8N)9[Tb5(SO4)12]·2H2O. Such compounds are of research interest due to their photoluminescent properties.
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