Tetraethylsilane is an organosilicon compound with the chemical formula Si(CH2CH3)4. It is a colorless liquid. Under standard conditions, it does not react with water, air, nitric acid or concentrated potassium hydroxide. Its vapor density is 4.98, relative to air (air = 1).
Synthesis The synthesis of tetraethylsilane by reacting silicon tetrachloride with diethylmercury or diethylzinc in an ampoule at 140–160 °C (284–320 °F) was first reported in 1863 by Charles Friedel and James Mason Crafts.
SiCl4 + 2 Zn(CH2CH3)2 → Si(CH2CH3)4 + 2 ZnCl2
Uses Tetraethylsilane reacts with halides of the boron group elements, such as boron tribromide or gallium trichloride with high yield and purity to form the corresponding dihaloethyl compound.
Si(CH2CH3)4 + BBr3 → (CH3CH2)3SiBr + CH3CH2BBr2 Si(CH2CH3)4 + GaCl3 → (CH3CH2)3SiCl + CH3CH2GaCl2
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