Tetraiodine nonoxide is an iodine oxide with the chemical formula I4O9.
Preparation Tetraiodine nonoxide can be produced by reacting ozone and iodine in carbon tetrachloride at −78 °C:
2 I2 + 9 O3 → I4O9 + 9 O2 It can also be produced by heating iodic acid and phosphoric acid together:
8 HIO3 → 2 I4O9 + 4 H2O + O2
Properties Tetraiodine nonoxide is a light yellow solid that can easily hydrolyze. It decomposes above 75 °C:
4 I4O9 → 6 I2O5 + 2 I2 + 3 O2 Like diiodine tetroxide, tetraiodine nonoxide contains both I(III) and I(V), and disproportionates to iodate and iodide under alkaline conditions:
3 I4O9 + 12 HO− → I− + 11 IO−3 + 6 H2O It reacts with water to form iodic acid and iodine:
4 I4O9 + 9 H2O → 18 HIO3 + I2
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